Structural Impact of Platinum on the Incommensurably Modulated γ-Brass Related Composite Structure Pd(15)Zn(54).
(2012) In Inorganic Chemistry 51(18). p.9893-9901- Abstract
- The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of... (More)
- The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of Zn atoms running along the center of the column. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3124287
- author
- Jana, Partha LU and Lidin, Sven LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Inorganic Chemistry
- volume
- 51
- issue
- 18
- pages
- 9893 - 9901
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000308778000037
- pmid:22950831
- scopus:84866396845
- pmid:22950831
- ISSN
- 1520-510X
- DOI
- 10.1021/ic301326p
- language
- English
- LU publication?
- yes
- id
- ac701191-5868-4d5d-abbc-e02870623cfa (old id 3124287)
- date added to LUP
- 2016-04-01 11:13:54
- date last changed
- 2022-01-26 06:24:19
@article{ac701191-5868-4d5d-abbc-e02870623cfa, abstract = {{The crystal structure of three incommensurately modulated γ-brass related composite structures in the Pd-Zn-Pt system has been solved from X-ray single crystal diffraction data using a 3 + 1-dimensional super space description. The compounds Pt(x)Pd(15-x)Zn(54) (x ≈ 6, 7, 10) crystallize in orthorhombic superspace group Fmmm(α00)0s0 (F = [(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the following fundamental cell dimensions: a = 4.265(1) Å, b = 9.132(1) Å, c = 12.928(2) Å, q ≈ 0.629a*; a = 4.284(1) Å, b = 9.151(2) Å, c = 12.948(4) Å, q ≈ 0.628a*; and a = 4.288(1) Å, b = 9.140(4) Å, c = 12.926(7) Å, q ≈ 0.627a*. Each structure is built by two sub-lattices-pentagonal antiprismatic columns parallel to [100] and a zigzag chain of Zn atoms running along the center of the column.}}, author = {{Jana, Partha and Lidin, Sven}}, issn = {{1520-510X}}, language = {{eng}}, number = {{18}}, pages = {{9893--9901}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Inorganic Chemistry}}, title = {{Structural Impact of Platinum on the Incommensurably Modulated γ-Brass Related Composite Structure Pd(15)Zn(54).}}, url = {{http://dx.doi.org/10.1021/ic301326p}}, doi = {{10.1021/ic301326p}}, volume = {{51}}, year = {{2012}}, }