Crystalline Iron Oxohalide Nanotube Pea Pods
(2012) In European Journal of Inorganic Chemistry p.3971-3974- Abstract
- Compounds Fe7Sb3(PO4)3O6Cl3 and Fe7Sb3(PO4)3O6Br3 are the first iron phosphates containing SbIII. They were synthesized by chemical vapor transport reactions, and their crystal structures were characterized by single-crystal X-ray diffraction. The compounds are isostructural and crystallize in the orthorhombic space group Pnma. Tubular Fe7(PO4)3O6X3 units (X = Cl, Br) are linked by SbO4 groups to build up a framework. The tubular units consist of an outer part made up of [FeO5X] octahedra where the Fe atoms are arranged to resemble a nanotube. Inside the tubes there are phosphate groups, and at the very center there is a chain of face-sharing [FeO6] octahedra.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3139215
- author
- Zimmermann, Iwan ; Johnsson, Mats and Lidin, Sven LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Oxohalides, Structure elucidation, Nanostructures, Iron, Antimony
- in
- European Journal of Inorganic Chemistry
- issue
- 25
- pages
- 3971 - 3974
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- wos:000307950500002
- scopus:84865575393
- ISSN
- 1099-0682
- DOI
- 10.1002/ejic.201200205
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 69ad1101-16dd-449d-a595-504b4f18845e (old id 3139215)
- date added to LUP
- 2016-04-01 09:52:39
- date last changed
- 2022-01-25 17:35:52
@article{69ad1101-16dd-449d-a595-504b4f18845e, abstract = {{Compounds Fe7Sb3(PO4)3O6Cl3 and Fe7Sb3(PO4)3O6Br3 are the first iron phosphates containing SbIII. They were synthesized by chemical vapor transport reactions, and their crystal structures were characterized by single-crystal X-ray diffraction. The compounds are isostructural and crystallize in the orthorhombic space group Pnma. Tubular Fe7(PO4)3O6X3 units (X = Cl, Br) are linked by SbO4 groups to build up a framework. The tubular units consist of an outer part made up of [FeO5X] octahedra where the Fe atoms are arranged to resemble a nanotube. Inside the tubes there are phosphate groups, and at the very center there is a chain of face-sharing [FeO6] octahedra.}}, author = {{Zimmermann, Iwan and Johnsson, Mats and Lidin, Sven}}, issn = {{1099-0682}}, keywords = {{Oxohalides; Structure elucidation; Nanostructures; Iron; Antimony}}, language = {{eng}}, number = {{25}}, pages = {{3971--3974}}, publisher = {{John Wiley & Sons Inc.}}, series = {{European Journal of Inorganic Chemistry}}, title = {{Crystalline Iron Oxohalide Nanotube Pea Pods}}, url = {{http://dx.doi.org/10.1002/ejic.201200205}}, doi = {{10.1002/ejic.201200205}}, year = {{2012}}, }