Surface phase diagram and temperature induced phase transitions of Sn/Cu(100)
(2006) Eight International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures and the Thirteenth International Congress on Thin Films - ACSIN8/ICTF13 252(15). p.5331-5334- Abstract
- Room temperature deposition of Sn on Cu(100) gives rise to a rich variety of surface reconstructions in the submonolayer coverage range. In this work, we report a detailed investigation on the phases appearing and their temperature stability range by using low-energy electron diffraction and surface X-ray diffraction. Previously reported reconstructions in the submonolayer range are p(2 x 2) (for 0.2 ML), p(2 x 6) (for 0.33 ML), (3 root 2 x root 2)R45 degrees (for 0.5 ML), and c(4 x 4) (for 0.65 ML). We find a new phase with a ((-4)(0) (2)(4)) structure for a coverage of 0.45 ML. Furthermore, we analyze the temperature stability of all phases. We find that two phases exhibit a temperature induced reversible phase transition: the (3 root 2... (More)
- Room temperature deposition of Sn on Cu(100) gives rise to a rich variety of surface reconstructions in the submonolayer coverage range. In this work, we report a detailed investigation on the phases appearing and their temperature stability range by using low-energy electron diffraction and surface X-ray diffraction. Previously reported reconstructions in the submonolayer range are p(2 x 2) (for 0.2 ML), p(2 x 6) (for 0.33 ML), (3 root 2 x root 2)R45 degrees (for 0.5 ML), and c(4 x 4) (for 0.65 ML). We find a new phase with a ((-4)(0) (2)(4)) structure for a coverage of 0.45 ML. Furthermore, we analyze the temperature stability of all phases. We find that two phases exhibit a temperature induced reversible phase transition: the (3 root 2 x root 2)R45 degrees phase becomes (root 2 x root 2)R45 degrees phase above 360 K, and the new ((-4)(0) (2)(4)) phase becomes p(2 x 2) also above 360 K. The origin of these two-phase transitions is discussed. (c) 2005 Elsevier B.V. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/405762
- author
- Martinez-Blanco, J ; Joco, V ; Segovia, P ; Thiagarajan, Balasubramanian LU and Michel, EG
- organization
- publishing date
- 2006
- type
- Chapter in Book/Report/Conference proceeding
- publication status
- published
- subject
- keywords
- phase transitions, copper, tin, surface X-ray diffraction, low energy electron diffraction (LEED), surface reconstruction, (SXRD)
- host publication
- Proceedings of the Eight International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures and the Thirteenth International Congress on Thin Films - ACSIN8/ICTF13 (Applied Surface Science)
- volume
- 252
- issue
- 15
- pages
- 5331 - 5334
- publisher
- Elsevier
- conference name
- Eight International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures and the Thirteenth International Congress on Thin Films - ACSIN8/ICTF13
- conference location
- Stockholm, Sweden
- conference dates
- 2005-06-20 - 2005-06-23
- external identifiers
-
- wos:000238623300022
- scopus:33746801957
- ISSN
- 0169-4332
- 1873-5584
- DOI
- 10.1016/j.apsusc.2005.12.011
- language
- English
- LU publication?
- yes
- id
- c191dbcd-0341-4f4d-9dc2-d35e26841568 (old id 405762)
- date added to LUP
- 2016-04-01 12:29:08
- date last changed
- 2024-10-09 12:07:09
@inproceedings{c191dbcd-0341-4f4d-9dc2-d35e26841568,
abstract = {{Room temperature deposition of Sn on Cu(100) gives rise to a rich variety of surface reconstructions in the submonolayer coverage range. In this work, we report a detailed investigation on the phases appearing and their temperature stability range by using low-energy electron diffraction and surface X-ray diffraction. Previously reported reconstructions in the submonolayer range are p(2 x 2) (for 0.2 ML), p(2 x 6) (for 0.33 ML), (3 root 2 x root 2)R45 degrees (for 0.5 ML), and c(4 x 4) (for 0.65 ML). We find a new phase with a ((-4)(0) (2)(4)) structure for a coverage of 0.45 ML. Furthermore, we analyze the temperature stability of all phases. We find that two phases exhibit a temperature induced reversible phase transition: the (3 root 2 x root 2)R45 degrees phase becomes (root 2 x root 2)R45 degrees phase above 360 K, and the new ((-4)(0) (2)(4)) phase becomes p(2 x 2) also above 360 K. The origin of these two-phase transitions is discussed. (c) 2005 Elsevier B.V. All rights reserved.}},
author = {{Martinez-Blanco, J and Joco, V and Segovia, P and Thiagarajan, Balasubramanian and Michel, EG}},
booktitle = {{Proceedings of the Eight International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures and the Thirteenth International Congress on Thin Films - ACSIN8/ICTF13 (Applied Surface Science)}},
issn = {{0169-4332}},
keywords = {{phase transitions; copper; tin; surface X-ray diffraction; low energy electron diffraction (LEED); surface reconstruction; (SXRD)}},
language = {{eng}},
number = {{15}},
pages = {{5331--5334}},
publisher = {{Elsevier}},
title = {{Surface phase diagram and temperature induced phase transitions of Sn/Cu(100)}},
url = {{http://dx.doi.org/10.1016/j.apsusc.2005.12.011}},
doi = {{10.1016/j.apsusc.2005.12.011}},
volume = {{252}},
year = {{2006}},
}