Rate coefficients for the chemical reactions of CH2F2, CHClF2, CH2FCF3 and CH3CCl3 with O(D-1) at 298 K
Heimdal Nilsson, Elna LU
; Andersen, V. F.
; Nielsen, O. J.
and Johnson, M. S.
(2012)
In Chemical Physics Letters
554.
p.27-32
- Abstract
- The rate coefficients for the chemical reactions (species loss rates, quenching excluded) of the refrigerants CH2F2 (HFC-32), CHClF2 (HFC-22) and CH2FCF3 (HFC-134a), and the solvent CH3CCl3 with O(D-1) are determined relative to CH4 + O(D-1) at 298 K. The resulting rates k(CH2F2 + O(D-1)) = (4.78 +/- 1.03) x 10 (11) cm(3) molecule (1) s (1), k(CHClF2 + O(D-1)) = (8.69 +/- 1.72) x 10 (11) cm(3) molecule (1) s (1), k(CH2FCF3 + O(D-1)) = (6.10 +/- 1.43) x 10 (11) cm(3) molecule (1) s (1) are compared to available literature data. The reaction rate of 1,1,1-trichloroethane with O(D-1) is determined for the first time, k(CH3CCl3 + O(D-1)) = (2.93 +/- 1.20) x 10 (10) cm(3) molecule (1) s (1).
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4939980
- author
- Heimdal Nilsson, Elna
LU
; Andersen, V. F.
; Nielsen, O. J.
and Johnson, M. S.
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 554
- pages
- 27 - 32
- publisher
- Elsevier
- external identifiers
-
- wos:000311039500004
- scopus:84869085537
- ISSN
- 0009-2614
- DOI
- 10.1016/j.cplett.2012.10.001
- language
- English
- LU publication?
- yes
- id
- 54fc40f2-fbcf-474c-9a6d-c89dc0cffb0f (old id 4939980)
- date added to LUP
- 2016-04-01 15:03:48
- date last changed
- 2022-01-28 03:54:12
@article{54fc40f2-fbcf-474c-9a6d-c89dc0cffb0f,
abstract = {{The rate coefficients for the chemical reactions (species loss rates, quenching excluded) of the refrigerants CH2F2 (HFC-32), CHClF2 (HFC-22) and CH2FCF3 (HFC-134a), and the solvent CH3CCl3 with O(D-1) are determined relative to CH4 + O(D-1) at 298 K. The resulting rates k(CH2F2 + O(D-1)) = (4.78 +/- 1.03) x 10 (11) cm(3) molecule (1) s (1), k(CHClF2 + O(D-1)) = (8.69 +/- 1.72) x 10 (11) cm(3) molecule (1) s (1), k(CH2FCF3 + O(D-1)) = (6.10 +/- 1.43) x 10 (11) cm(3) molecule (1) s (1) are compared to available literature data. The reaction rate of 1,1,1-trichloroethane with O(D-1) is determined for the first time, k(CH3CCl3 + O(D-1)) = (2.93 +/- 1.20) x 10 (10) cm(3) molecule (1) s (1).}},
author = {{Heimdal Nilsson, Elna and Andersen, V. F. and Nielsen, O. J. and Johnson, M. S.}},
issn = {{0009-2614}},
language = {{eng}},
pages = {{27--32}},
publisher = {{Elsevier}},
series = {{Chemical Physics Letters}},
title = {{Rate coefficients for the chemical reactions of CH2F2, CHClF2, CH2FCF3 and CH3CCl3 with O(D-1) at 298 K}},
url = {{http://dx.doi.org/10.1016/j.cplett.2012.10.001}},
doi = {{10.1016/j.cplett.2012.10.001}},
volume = {{554}},
year = {{2012}},
}