The structures of X2[(Mo6Cl8)Cl 6]·nH2O, X=NH4, K, Rb, Cs
(2004) In Solid State Sciences 6(6). p.509-517- Abstract
The title compounds were synthesized from MoCl2 and the appropriate commercial chlorides and their structures were solved by a combination of single crystal X-ray diffraction analysis and theoretical methods. The NH4, K and Rb compounds are essentially isostructural, and crystallize in space group Ia (No. 9) with the cell parameters (in Å) a=9.173(1), b=14.986(2), c=17.505(3), β=92.94(2)°(NH4); a=9.140(4), b=14.852(5), c=17.445(11), β=93.48(6)°(K); a=9.215(1), b=14.941(3), c=17.532(2), β=92.70(1)°(Rb); while the Cs compound crystallizes in space group P21/n (No. 14) with the cell dimensions a=9.771(3), b=12.984(4), c=21.535(4), β=90.81(3)°.
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- author
- Flemström, A. ; Hirsch, T. K. ; Eriksson, L. LU and Lidin, S. LU
- publishing date
- 2004-06-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Molybdenum (II) clusters
- in
- Solid State Sciences
- volume
- 6
- issue
- 6
- pages
- 9 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:2442595237
- ISSN
- 1293-2558
- DOI
- 10.1016/j.solidstatesciences.2004.03.005
- language
- English
- LU publication?
- no
- id
- 5bb6bf8b-07bd-4c65-8a0c-ef822ba8e59c
- date added to LUP
- 2019-04-08 15:26:14
- date last changed
- 2022-01-31 18:51:57
@article{5bb6bf8b-07bd-4c65-8a0c-ef822ba8e59c, abstract = {{<p>The title compounds were synthesized from MoCl<sub>2</sub> and the appropriate commercial chlorides and their structures were solved by a combination of single crystal X-ray diffraction analysis and theoretical methods. The NH<sub>4</sub>, K and Rb compounds are essentially isostructural, and crystallize in space group Ia (No. 9) with the cell parameters (in Å) a=9.173(1), b=14.986(2), c=17.505(3), β=92.94(2)°(NH<sub>4</sub>); a=9.140(4), b=14.852(5), c=17.445(11), β=93.48(6)°(K); a=9.215(1), b=14.941(3), c=17.532(2), β=92.70(1)°(Rb); while the Cs compound crystallizes in space group P2<sub>1</sub>/n (No. 14) with the cell dimensions a=9.771(3), b=12.984(4), c=21.535(4), β=90.81(3)°.</p>}}, author = {{Flemström, A. and Hirsch, T. K. and Eriksson, L. and Lidin, S.}}, issn = {{1293-2558}}, keywords = {{Molybdenum (II) clusters}}, language = {{eng}}, month = {{06}}, number = {{6}}, pages = {{509--517}}, publisher = {{Elsevier}}, series = {{Solid State Sciences}}, title = {{The structures of X<sub>2</sub>[(Mo<sub>6</sub>Cl<sub>8</sub>)Cl <sub>6</sub>]·nH<sub>2</sub>O, X=NH<sub>4</sub>, K, Rb, Cs}}, url = {{http://dx.doi.org/10.1016/j.solidstatesciences.2004.03.005}}, doi = {{10.1016/j.solidstatesciences.2004.03.005}}, volume = {{6}}, year = {{2004}}, }