Diels-Alder adducts derived from the natural phthalide Z-ligustilide
(2007) In Tetrahedron Letters 48(24). p.4215-4218- Abstract
- Z-Ligustilide, a naturally occurring phthalide isolated from Ligusticum porteri, underwent Diels-Alder reactions with different dienophiles yielding novel tricyclic products with potentially interesting biological properties. Where selectivity was possible, the reactions performed showed regio- and stereoselectivity. The experimental results with ethyl acrylate were compared with the selectivity predicted by ab initio calculations.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/648643
- author
- Lager, Erik LU ; Sundin, Anders LU ; Toscano, Ruben A. ; Delgado, Guillermo and Sterner, Olov LU
- organization
- publishing date
- 2007
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- STAT3, Z-ligustilide, galiellalactone, ab initio, Diels-Alder
- in
- Tetrahedron Letters
- volume
- 48
- issue
- 24
- pages
- 4215 - 4218
- publisher
- Elsevier
- external identifiers
-
- wos:000247225800014
- scopus:34249025719
- ISSN
- 0040-4039
- DOI
- 10.1016/j.tetlet.2007.04.059
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- eafcc48d-5f20-4bc4-b396-7f149f510656 (old id 648643)
- date added to LUP
- 2016-04-01 16:18:57
- date last changed
- 2022-01-28 18:50:26
@article{eafcc48d-5f20-4bc4-b396-7f149f510656, abstract = {{Z-Ligustilide, a naturally occurring phthalide isolated from Ligusticum porteri, underwent Diels-Alder reactions with different dienophiles yielding novel tricyclic products with potentially interesting biological properties. Where selectivity was possible, the reactions performed showed regio- and stereoselectivity. The experimental results with ethyl acrylate were compared with the selectivity predicted by ab initio calculations.}}, author = {{Lager, Erik and Sundin, Anders and Toscano, Ruben A. and Delgado, Guillermo and Sterner, Olov}}, issn = {{0040-4039}}, keywords = {{STAT3; Z-ligustilide; galiellalactone; ab initio; Diels-Alder}}, language = {{eng}}, number = {{24}}, pages = {{4215--4218}}, publisher = {{Elsevier}}, series = {{Tetrahedron Letters}}, title = {{Diels-Alder adducts derived from the natural phthalide Z-ligustilide}}, url = {{http://dx.doi.org/10.1016/j.tetlet.2007.04.059}}, doi = {{10.1016/j.tetlet.2007.04.059}}, volume = {{48}}, year = {{2007}}, }