Experimental study on thermal runaway evolution and toxicity hazard of lithium-ion batteries in a tunnel under longitudinal air flow
(2025) In Journal of Energy Storage 114.- Abstract
The widespread adoption of lithium-ion batteries (LIBs) for energy storage has introduced significant fire risks, particularly in confined and restricted environments such as tunnels. This study investigated thermal runaway (TR) behavior in a model tunnel at ventilation speeds ranging from 0 m/s to 2.5 m/s, using LiFePO4 (LFP) and LiNixCoyMnzO2 (NCM) batteries. The experiments identified two critical phases (e.g., safe venting and uncontrollable TR) that govern flame propagation within the tunnel. NCM batteries exhibited a maximum ceiling temperature exceeding 127 °C at wind speeds below 2.0 m/s, while LFP cells surpassed this threshold even without ventilation. Furthermore, CO emissions from... (More)
The widespread adoption of lithium-ion batteries (LIBs) for energy storage has introduced significant fire risks, particularly in confined and restricted environments such as tunnels. This study investigated thermal runaway (TR) behavior in a model tunnel at ventilation speeds ranging from 0 m/s to 2.5 m/s, using LiFePO4 (LFP) and LiNixCoyMnzO2 (NCM) batteries. The experiments identified two critical phases (e.g., safe venting and uncontrollable TR) that govern flame propagation within the tunnel. NCM batteries exhibited a maximum ceiling temperature exceeding 127 °C at wind speeds below 2.0 m/s, while LFP cells surpassed this threshold even without ventilation. Furthermore, CO emissions from LFP battery TR were significantly reduced (~90 %) with an increase in ventilation speed to 2.0 m/s. However, mitigating the toxic CO emissions from NCM battery TR required substantially higher ventilation speeds. The maximum ceiling temperature rise due to longitudinal airflow was characterized using a power function. These results contribute to a deeper understanding of the hazards posed by battery TR in confined spaces and offer insights into enhancing the resilience of critical urban infrastructure.
(Less)
- author
- Zhu, Nannan ; Tang, Fei ; Peng, Xinyu ; Sun, Xiepeng ; Hu, Longhua and Mcnamee, Margaret LU
- organization
- publishing date
- 2025-04
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Li-ion battery fire, Longitudinal ventilation, Thermal runaway, Toxicity, Tunnel fire
- in
- Journal of Energy Storage
- volume
- 114
- article number
- 115651
- publisher
- Elsevier
- external identifiers
-
- scopus:85217088962
- ISSN
- 2352-1538
- DOI
- 10.1016/j.est.2025.115651
- language
- English
- LU publication?
- yes
- id
- 6dab0cb2-b8a9-496d-890e-419771389f74
- date added to LUP
- 2025-03-17 15:41:16
- date last changed
- 2025-04-04 14:20:59
@article{6dab0cb2-b8a9-496d-890e-419771389f74, abstract = {{<p>The widespread adoption of lithium-ion batteries (LIBs) for energy storage has introduced significant fire risks, particularly in confined and restricted environments such as tunnels. This study investigated thermal runaway (TR) behavior in a model tunnel at ventilation speeds ranging from 0 m/s to 2.5 m/s, using LiFePO<sub>4</sub> (LFP) and LiNi<sub>x</sub>Co<sub>y</sub>MnzO<sub>2</sub> (NCM) batteries. The experiments identified two critical phases (e.g., safe venting and uncontrollable TR) that govern flame propagation within the tunnel. NCM batteries exhibited a maximum ceiling temperature exceeding 127 °C at wind speeds below 2.0 m/s, while LFP cells surpassed this threshold even without ventilation. Furthermore, CO emissions from LFP battery TR were significantly reduced (~90 %) with an increase in ventilation speed to 2.0 m/s. However, mitigating the toxic CO emissions from NCM battery TR required substantially higher ventilation speeds. The maximum ceiling temperature rise due to longitudinal airflow was characterized using a power function. These results contribute to a deeper understanding of the hazards posed by battery TR in confined spaces and offer insights into enhancing the resilience of critical urban infrastructure.</p>}}, author = {{Zhu, Nannan and Tang, Fei and Peng, Xinyu and Sun, Xiepeng and Hu, Longhua and Mcnamee, Margaret}}, issn = {{2352-1538}}, keywords = {{Li-ion battery fire; Longitudinal ventilation; Thermal runaway; Toxicity; Tunnel fire}}, language = {{eng}}, publisher = {{Elsevier}}, series = {{Journal of Energy Storage}}, title = {{Experimental study on thermal runaway evolution and toxicity hazard of lithium-ion batteries in a tunnel under longitudinal air flow}}, url = {{http://dx.doi.org/10.1016/j.est.2025.115651}}, doi = {{10.1016/j.est.2025.115651}}, volume = {{114}}, year = {{2025}}, }