UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO
Gratien, Aline ; Nilsson, Elna LU
; Doussin, Jean-francois
; Johnson, Matthew S.
; Nielsen, Claus J.
; Stenstrøm, Yngve
and Picquet-Varrault, Bénédicte
(2007)
In The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
111(45).
p.11506-11513
- Abstract
- UV (240-370 nm) and IR (3200-1500 cm-1) absorption cross-sections of HCHO, HCDO, and DCDO in a
bath gas of N2 at atmospheric pressure and 296 K are reported from simultaneous measurements in the two
spectral regions. Cross-sections were placed on an absolute scale through quantitative conversion of
formaldehyde to CO and HCOOH by titration with Br atoms, also monitored by FTIR. The integrated UV
absorption cross-sections of HCHO, HCDO, and DCDO are equal to within the experimental uncertainty.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/9e690c71-f5da-45fe-a927-b9634ea15059
- author
- Gratien, Aline
; Nilsson, Elna
LU
; Doussin, Jean-francois
; Johnson, Matthew S.
; Nielsen, Claus J.
; Stenstrøm, Yngve
and Picquet-Varrault, Bénédicte
- publishing date
- 2007-11-01
- type
- Contribution to journal
- publication status
- published
- in
- The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
- volume
- 111
- issue
- 45
- pages
- 11506 - 11513
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:36549037467
- ISSN
- 1089-5639
- DOI
- 10.1021/jp074288r
- language
- English
- LU publication?
- no
- id
- 9e690c71-f5da-45fe-a927-b9634ea15059
- alternative location
- https://pubs.acs.org/doi/10.1021/jp074288r
- date added to LUP
- 2019-05-15 11:06:00
- date last changed
- 2025-10-14 10:51:51
@article{9e690c71-f5da-45fe-a927-b9634ea15059,
abstract = {{UV (240-370 nm) and IR (3200-1500 cm-1) absorption cross-sections of HCHO, HCDO, and DCDO in a<br/>bath gas of N2 at atmospheric pressure and 296 K are reported from simultaneous measurements in the two<br/>spectral regions. Cross-sections were placed on an absolute scale through quantitative conversion of<br/>formaldehyde to CO and HCOOH by titration with Br atoms, also monitored by FTIR. The integrated UV<br/>absorption cross-sections of HCHO, HCDO, and DCDO are equal to within the experimental uncertainty.}},
author = {{Gratien, Aline and Nilsson, Elna and Doussin, Jean-francois and Johnson, Matthew S. and Nielsen, Claus J. and Stenstrøm, Yngve and Picquet-Varrault, Bénédicte}},
issn = {{1089-5639}},
language = {{eng}},
month = {{11}},
number = {{45}},
pages = {{11506--11513}},
publisher = {{The American Chemical Society (ACS)}},
series = {{The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory}},
title = {{UV and IR Absorption Cross-sections of HCHO, HCDO, and DCDO}},
url = {{http://dx.doi.org/10.1021/jp074288r}},
doi = {{10.1021/jp074288r}},
volume = {{111}},
year = {{2007}},
}