Nanocarbon oxidation in the environmental transmission electron microscope : Disentangling the role of the electron beam
(2024) In Carbon 218.- Abstract
Environmental transmission electron microscopy (ETEM) can provide unique insights into nanocarbon oxidation processes through atomic resolution and real time imaging of materials at high temperatures in reactive atmospheres. However, the electron beam can also influence the reaction rates, and even alter the processes entirely, complicating the interpretation of the in situ observations. Many mechanisms have been proposed to account for the impact of the electron beam, predominantly involving ionization of the oxidative gases to form more reactive species. However, these mechanisms have not been critically evaluated and compared to predictions from theory. Here, we evaluate the impact of the electron beam both qualitatively (oxidation... (More)
Environmental transmission electron microscopy (ETEM) can provide unique insights into nanocarbon oxidation processes through atomic resolution and real time imaging of materials at high temperatures in reactive atmospheres. However, the electron beam can also influence the reaction rates, and even alter the processes entirely, complicating the interpretation of the in situ observations. Many mechanisms have been proposed to account for the impact of the electron beam, predominantly involving ionization of the oxidative gases to form more reactive species. However, these mechanisms have not been critically evaluated and compared to predictions from theory. Here, we evaluate the impact of the electron beam both qualitatively (oxidation mode and spatial extent) and quantitatively (oxidation rates), using high resolution imaging and electron energy loss spectroscopy, at different electron energies and dose rates. We demonstrate that transient defects generated by elastic scattering, forming highly active sites for carbon abstraction by oxygen, is the main mechanism for the enhanced oxidation rates observed in situ. This is evident from an insensitivity to electron energy and saturation of the effects at high electron dose rates. To avoid undue influence of the electron beam in future ETEM studies, we therefore recommend conditions where the intrinsic oxidation dominates over the beam-enhanced oxidation (note that no conditions are completely “safe”) and extensive comparisons with other methods.
(Less)
- author
- Wahlqvist, David LU ; Mases, Mattias ; Jacobsson, Daniel LU ; Wiinikka, Henrik and Ek, Martin LU
- organization
- publishing date
- 2024-01-31
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Carbon black, EELS, Electron beam effects, ETEM, Nanocarbons, Oxidation
- in
- Carbon
- volume
- 218
- article number
- 118686
- pages
- 10 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:85178132166
- ISSN
- 0008-6223
- DOI
- 10.1016/j.carbon.2023.118686
- language
- English
- LU publication?
- yes
- id
- 04cf3eab-5823-4c18-b726-1bcaf4b40f24
- date added to LUP
- 2023-12-11 11:39:32
- date last changed
- 2024-01-31 10:06:01
@article{04cf3eab-5823-4c18-b726-1bcaf4b40f24, abstract = {{<p>Environmental transmission electron microscopy (ETEM) can provide unique insights into nanocarbon oxidation processes through atomic resolution and real time imaging of materials at high temperatures in reactive atmospheres. However, the electron beam can also influence the reaction rates, and even alter the processes entirely, complicating the interpretation of the in situ observations. Many mechanisms have been proposed to account for the impact of the electron beam, predominantly involving ionization of the oxidative gases to form more reactive species. However, these mechanisms have not been critically evaluated and compared to predictions from theory. Here, we evaluate the impact of the electron beam both qualitatively (oxidation mode and spatial extent) and quantitatively (oxidation rates), using high resolution imaging and electron energy loss spectroscopy, at different electron energies and dose rates. We demonstrate that transient defects generated by elastic scattering, forming highly active sites for carbon abstraction by oxygen, is the main mechanism for the enhanced oxidation rates observed in situ. This is evident from an insensitivity to electron energy and saturation of the effects at high electron dose rates. To avoid undue influence of the electron beam in future ETEM studies, we therefore recommend conditions where the intrinsic oxidation dominates over the beam-enhanced oxidation (note that no conditions are completely “safe”) and extensive comparisons with other methods.</p>}}, author = {{Wahlqvist, David and Mases, Mattias and Jacobsson, Daniel and Wiinikka, Henrik and Ek, Martin}}, issn = {{0008-6223}}, keywords = {{Carbon black; EELS; Electron beam effects; ETEM; Nanocarbons; Oxidation}}, language = {{eng}}, month = {{01}}, publisher = {{Elsevier}}, series = {{Carbon}}, title = {{Nanocarbon oxidation in the environmental transmission electron microscope : Disentangling the role of the electron beam}}, url = {{http://dx.doi.org/10.1016/j.carbon.2023.118686}}, doi = {{10.1016/j.carbon.2023.118686}}, volume = {{218}}, year = {{2024}}, }