Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]
(2010) In Acta Crystallographica. Section C: Crystal Structure Communications 66. p.227-230- Abstract
- The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the... (More)
- The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1677239
- author
- Jalilian, Ehsan and Lidin, Sven LU
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica. Section C: Crystal Structure Communications
- volume
- 66
- pages
- 227 - 230
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000280708100009
- scopus:77955464014
- pmid:20679711
- ISSN
- 0108-2701
- DOI
- 10.1107/S0108270110027149
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 7eaeb347-2c53-4b53-948e-c6510ef086b5 (old id 1677239)
- date added to LUP
- 2016-04-01 14:44:03
- date last changed
- 2022-04-06 20:13:14
@article{7eaeb347-2c53-4b53-948e-c6510ef086b5, abstract = {{The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis.}}, author = {{Jalilian, Ehsan and Lidin, Sven}}, issn = {{0108-2701}}, language = {{eng}}, pages = {{227--230}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica. Section C: Crystal Structure Communications}}, title = {{Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]}}, url = {{http://dx.doi.org/10.1107/S0108270110027149}}, doi = {{10.1107/S0108270110027149}}, volume = {{66}}, year = {{2010}}, }