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Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]

Jalilian, Ehsan and Lidin, Sven LU (2010) In Acta Crystallographica. Section C: Crystal Structure Communications 66. p.227-230
Abstract
The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the... (More)
The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis. (Less)
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
66
pages
227 - 230
publisher
International Union of Crystallography
external identifiers
  • wos:000280708100009
  • scopus:77955464014
ISSN
0108-2701
DOI
10.1107/S0108270110027149
language
English
LU publication?
yes
id
7eaeb347-2c53-4b53-948e-c6510ef086b5 (old id 1677239)
date added to LUP
2010-09-21 15:49:45
date last changed
2018-05-29 10:19:11
@article{7eaeb347-2c53-4b53-948e-c6510ef086b5,
  abstract     = {The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis.},
  author       = {Jalilian, Ehsan and Lidin, Sven},
  issn         = {0108-2701},
  language     = {eng},
  pages        = {227--230},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica. Section C: Crystal Structure Communications},
  title        = {Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]},
  url          = {http://dx.doi.org/10.1107/S0108270110027149},
  volume       = {66},
  year         = {2010},
}