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Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.

Johnsson, Richard LU (2012) In Carbohydrate Research 353(Online 24 March 2012). p.92-95
Abstract
The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Carbohydrate Research
volume
353
issue
Online 24 March 2012
pages
92 - 95
publisher
Elsevier
external identifiers
  • wos:000304053900012
  • pmid:22533917
  • scopus:84861096808
ISSN
1873-426X
DOI
10.1016/j.carres.2012.03.016
language
English
LU publication?
yes
id
be34b210-aeb0-4f39-9047-68a81a33d067 (old id 2519040)
date added to LUP
2012-05-08 17:39:42
date last changed
2017-04-23 03:13:14
@article{be34b210-aeb0-4f39-9047-68a81a33d067,
  abstract     = {The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.},
  author       = {Johnsson, Richard},
  issn         = {1873-426X},
  language     = {eng},
  number       = {Online 24 March 2012},
  pages        = {92--95},
  publisher    = {Elsevier},
  series       = {Carbohydrate Research},
  title        = {Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.},
  url          = {http://dx.doi.org/10.1016/j.carres.2012.03.016},
  volume       = {353},
  year         = {2012},
}