A PdII Carbene Complex with Anthracene Side-Arms for π-Stacking on Reduced Graphene Oxide (rGO) : Activity towards Undirected C–H Oxygenation of Arenes
(2018) In European Journal of Inorganic Chemistry 2018(43). p.4742-4746- Abstract
An N-heterocyclic carbene palladium(II) complex containing two anthracene side arms was immobilized on the surface of reduced graphene oxide (rGO) by π-stacking. The activity of the homogeneous analogue and the supported complex in undirected C–H acetoxylation reaction of arenes was studied. The results show that the catalytic efficiency in acetoxylation of benzene is improved in the immobilized materials compared to the homogeneous analogue. According to XPS analysis, the immobilized catalyst maintains the original oxidation state of PdII after the catalytic reaction.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/328881cc-a6f2-41e3-b0c8-19d575a585c8
- author
- Majeed, Maitham H. LU ; Shayesteh, Payam LU ; Persson, Axel R. LU ; Wallenberg, L. Reine LU ; Schnadt, Joachim LU and Wendt, Ola F. LU
- organization
- publishing date
- 2018
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- C–H activation, N-heterocyclic carbenes, Palladium(II), Reduced graphene oxide supported Pd, Undirected acetoxylation
- in
- European Journal of Inorganic Chemistry
- volume
- 2018
- issue
- 43
- pages
- 5 pages
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- scopus:85057007302
- ISSN
- 1434-1948
- DOI
- 10.1002/ejic.201800978
- language
- English
- LU publication?
- yes
- id
- 328881cc-a6f2-41e3-b0c8-19d575a585c8
- date added to LUP
- 2018-12-03 13:49:32
- date last changed
- 2023-11-18 06:51:56
@article{328881cc-a6f2-41e3-b0c8-19d575a585c8, abstract = {{<p>An N-heterocyclic carbene palladium(II) complex containing two anthracene side arms was immobilized on the surface of reduced graphene oxide (rGO) by π-stacking. The activity of the homogeneous analogue and the supported complex in undirected C–H acetoxylation reaction of arenes was studied. The results show that the catalytic efficiency in acetoxylation of benzene is improved in the immobilized materials compared to the homogeneous analogue. According to XPS analysis, the immobilized catalyst maintains the original oxidation state of Pd<sup>II</sup> after the catalytic reaction.</p>}}, author = {{Majeed, Maitham H. and Shayesteh, Payam and Persson, Axel R. and Wallenberg, L. Reine and Schnadt, Joachim and Wendt, Ola F.}}, issn = {{1434-1948}}, keywords = {{C–H activation; N-heterocyclic carbenes; Palladium(II); Reduced graphene oxide supported Pd; Undirected acetoxylation}}, language = {{eng}}, number = {{43}}, pages = {{4742--4746}}, publisher = {{John Wiley & Sons Inc.}}, series = {{European Journal of Inorganic Chemistry}}, title = {{A Pd<sup>II</sup> Carbene Complex with Anthracene Side-Arms for π-Stacking on Reduced Graphene Oxide (rGO) : Activity towards Undirected C–H Oxygenation of Arenes}}, url = {{http://dx.doi.org/10.1002/ejic.201800978}}, doi = {{10.1002/ejic.201800978}}, volume = {{2018}}, year = {{2018}}, }