Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate

Spencer, Lara C. ; Bjelosevic, Haris LU ; Darkwa, James ; Elmroth, Sofi LU and Persson, Tina LU (2008) In Acta Crystallographica Section E: Structure Reports Online 64(1). p.164-1562
Abstract
The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
Please use this url to cite or link to this publication:
author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
platinum, dppf, X-ray, ferrocene, single-crystal, Pt
in
Acta Crystallographica Section E: Structure Reports Online
volume
64
issue
1
pages
164 - 1562
publisher
International Union of Crystallography
external identifiers
  • wos:000252049300136
  • scopus:37849004549
  • pmid:21200513
ISSN
1600-5368
DOI
10.1107/S1600536807065105
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Biochemistry and Structural Biology (S) (000006142)
id
72bb6e4f-98d7-409f-a3f7-e9a52ab64c51 (old id 750532)
alternative location
http://journals.iucr.org/e/issues/2008/01/00/hb2623/hb2623.pdf
date added to LUP
2016-04-01 15:06:37
date last changed
2022-01-28 04:32:09
@article{72bb6e4f-98d7-409f-a3f7-e9a52ab64c51,
  abstract     = {{The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.}},
  author       = {{Spencer, Lara C. and Bjelosevic, Haris and Darkwa, James and Elmroth, Sofi and Persson, Tina}},
  issn         = {{1600-5368}},
  keywords     = {{platinum; dppf; X-ray; ferrocene; single-crystal; Pt}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{164--1562}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica Section E: Structure Reports Online}},
  title        = {{{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate}},
  url          = {{https://lup.lub.lu.se/search/files/4344834/750632.pdf}},
  doi          = {{10.1107/S1600536807065105}},
  volume       = {{64}},
  year         = {{2008}},
}