{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate
(2008) In Acta Crystallographica Section E: Structure Reports Online 64(1). p.164-1562- Abstract
- The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/750532
- author
- Spencer, Lara C. ; Bjelosevic, Haris LU ; Darkwa, James ; Elmroth, Sofi LU and Persson, Tina LU
- organization
- publishing date
- 2008
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- platinum, dppf, X-ray, ferrocene, single-crystal, Pt
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 64
- issue
- 1
- pages
- 164 - 1562
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000252049300136
- scopus:37849004549
- pmid:21200513
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536807065105
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Biochemistry and Structural Biology (S) (000006142)
- id
- 72bb6e4f-98d7-409f-a3f7-e9a52ab64c51 (old id 750532)
- alternative location
- http://journals.iucr.org/e/issues/2008/01/00/hb2623/hb2623.pdf
- date added to LUP
- 2016-04-01 15:06:37
- date last changed
- 2022-01-28 04:32:09
@article{72bb6e4f-98d7-409f-a3f7-e9a52ab64c51, abstract = {{The dinuclear title compound, [FePtCl2(C17H14P)(C23H23NO3P)]x1.25CH2Cl2, has a slightly distorted cis-PtCl2P2 square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2) deg. about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong intermolecular O—H-O bonds resulting in R22(8) rings. A weak intramolecular N—H-Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.}}, author = {{Spencer, Lara C. and Bjelosevic, Haris and Darkwa, James and Elmroth, Sofi and Persson, Tina}}, issn = {{1600-5368}}, keywords = {{platinum; dppf; X-ray; ferrocene; single-crystal; Pt}}, language = {{eng}}, number = {{1}}, pages = {{164--1562}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica Section E: Structure Reports Online}}, title = {{{1-[1-(3-Carboxypropanamido)ethyl]-1',2-bis(diphenylphosphino)ferrocene-kappa2P,P'}dichloridoplatinum(II) dichloromethane 1.25-solvate}}, url = {{https://lup.lub.lu.se/search/files/4344834/750632.pdf}}, doi = {{10.1107/S1600536807065105}}, volume = {{64}}, year = {{2008}}, }