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Embedded sacrificial AlAs segments in GaAs nanowires for substrate reuse

Jafari Jam, R. LU ; Beech, Jason P. LU ; Zeng, Xulu LU ; Johansson, Jonas LU orcid ; Samuelson, Lars LU ; Pettersson, Håkan LU and Borgström, Magnus T. LU (2020) In Nanotechnology 31(20).
Abstract

We report on the use of a sacrificial AlAs segment to enable substrate reuse for nanowire synthesis. A silicon nitride template was deposited on a p-type GaAs substrate. Then a pattern was transferred to the substrate by nanoimprint lithography and reactive ion etching. Thermal evaporation was used to define Au seed particles. Metalorganic vapour phase epitaxy was used to grow AlAs-GaAs NWs in the vapour-liquid-solid growth mode. The yield of synthesised nanowires, compared to the number expected from the patterned template, was more than 80%. After growth, the nanowires were embedded in a polymer and mechanically removed from the parent substrate. The parent substrate was then immersed in an HCl:H2O (1:1) mixture to dissolve... (More)

We report on the use of a sacrificial AlAs segment to enable substrate reuse for nanowire synthesis. A silicon nitride template was deposited on a p-type GaAs substrate. Then a pattern was transferred to the substrate by nanoimprint lithography and reactive ion etching. Thermal evaporation was used to define Au seed particles. Metalorganic vapour phase epitaxy was used to grow AlAs-GaAs NWs in the vapour-liquid-solid growth mode. The yield of synthesised nanowires, compared to the number expected from the patterned template, was more than 80%. After growth, the nanowires were embedded in a polymer and mechanically removed from the parent substrate. The parent substrate was then immersed in an HCl:H2O (1:1) mixture to dissolve the remaining stub of the sacrificial AlAs segment. The pattern fidelity was preserved after peeling off the nanowires and cleaning, and the semiconductor surface was flat and ready for reuse. Au seed particles were then deposited on the substrate by use of pulse electrodeposition, which was selective to the openings in the growth template, and then nanowires were regrown. The yield of regrowth was less optimal compared to the first growth but the pattern was preserved. Our results show a promising approach to reduce the final cost of III-V nanowire based solar cells.

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author
; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
electrodeposition, nanowire, sacrificial segment, substrate reuse
in
Nanotechnology
volume
31
issue
20
article number
204002
publisher
IOP Publishing
external identifiers
  • pmid:32106108
  • scopus:85082168250
ISSN
0957-4484
DOI
10.1088/1361-6528/ab7680
language
English
LU publication?
yes
id
cc0598d8-1c3e-40ee-b4b1-29233fb9d807
date added to LUP
2020-04-02 14:12:47
date last changed
2024-04-03 04:06:56
@article{cc0598d8-1c3e-40ee-b4b1-29233fb9d807,
  abstract     = {{<p>We report on the use of a sacrificial AlAs segment to enable substrate reuse for nanowire synthesis. A silicon nitride template was deposited on a p-type GaAs substrate. Then a pattern was transferred to the substrate by nanoimprint lithography and reactive ion etching. Thermal evaporation was used to define Au seed particles. Metalorganic vapour phase epitaxy was used to grow AlAs-GaAs NWs in the vapour-liquid-solid growth mode. The yield of synthesised nanowires, compared to the number expected from the patterned template, was more than 80%. After growth, the nanowires were embedded in a polymer and mechanically removed from the parent substrate. The parent substrate was then immersed in an HCl:H<sub>2</sub>O (1:1) mixture to dissolve the remaining stub of the sacrificial AlAs segment. The pattern fidelity was preserved after peeling off the nanowires and cleaning, and the semiconductor surface was flat and ready for reuse. Au seed particles were then deposited on the substrate by use of pulse electrodeposition, which was selective to the openings in the growth template, and then nanowires were regrown. The yield of regrowth was less optimal compared to the first growth but the pattern was preserved. Our results show a promising approach to reduce the final cost of III-V nanowire based solar cells.</p>}},
  author       = {{Jafari Jam, R. and Beech, Jason P. and Zeng, Xulu and Johansson, Jonas and Samuelson, Lars and Pettersson, Håkan and Borgström, Magnus T.}},
  issn         = {{0957-4484}},
  keywords     = {{electrodeposition; nanowire; sacrificial segment; substrate reuse}},
  language     = {{eng}},
  number       = {{20}},
  publisher    = {{IOP Publishing}},
  series       = {{Nanotechnology}},
  title        = {{Embedded sacrificial AlAs segments in GaAs nanowires for substrate reuse}},
  url          = {{http://dx.doi.org/10.1088/1361-6528/ab7680}},
  doi          = {{10.1088/1361-6528/ab7680}},
  volume       = {{31}},
  year         = {{2020}},
}