Spin propensity in resonant photoemission of transition metal complexes
(2021) In Physical Review Research 3(3).- Abstract
- Resonant photoelectron spectroscopy (RPES) has been used to probe electronic structure properties of the closed-shell [FeII(CN)6]4− and open-shell [FeIII(CN)6]3− prototype transition metal complexes in aqueous solution. Site-selective Fe 2p (L-edge) RPES mapsprovide new insight into spin-coupling processes at the core-excited metal centers, with autoionization of [FeIII(CN)6]3− showing a dramatic (∼4×)
singlet versus triplet final-state enhancement. This shows that RPES
provides unique opportunities to study spin-dependent electronic
properties in transition metal based functional materials.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/6984ecf1-a147-47fd-9dcc-db54e94c80ec
- author
- Temperton, Robert H. LU ; Quevedo, Wilson ; Seidel, Robert ; Schnadt, Joachim LU ; Persson, Petter LU and Uhlig, Jens LU
- organization
- publishing date
- 2021-09
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review Research
- volume
- 3
- issue
- 3
- article number
- 033030
- publisher
- American Physical Society
- external identifiers
-
- scopus:85115903910
- ISSN
- 2643-1564
- DOI
- 10.1103/PhysRevResearch.3.033030
- language
- English
- LU publication?
- yes
- additional info
- Publisher Copyright: © 2021 authors. Published by the American Physical Society.
- id
- 6984ecf1-a147-47fd-9dcc-db54e94c80ec
- date added to LUP
- 2021-10-13 16:01:37
- date last changed
- 2023-11-08 21:06:01
@article{6984ecf1-a147-47fd-9dcc-db54e94c80ec, abstract = {{Resonant photoelectron spectroscopy (RPES) has been used to probe electronic structure properties of the closed-shell [FeII(CN)6]4− and open-shell [FeIII(CN)6]3− prototype transition metal complexes in aqueous solution. Site-selective Fe 2p (L-edge) RPES mapsprovide new insight into spin-coupling processes at the core-excited metal centers, with autoionization of [FeIII(CN)6]3− showing a dramatic (∼4×)<br> singlet versus triplet final-state enhancement. This shows that RPES <br> provides unique opportunities to study spin-dependent electronic <br> properties in transition metal based functional materials.}}, author = {{Temperton, Robert H. and Quevedo, Wilson and Seidel, Robert and Schnadt, Joachim and Persson, Petter and Uhlig, Jens}}, issn = {{2643-1564}}, language = {{eng}}, number = {{3}}, publisher = {{American Physical Society}}, series = {{Physical Review Research}}, title = {{Spin propensity in resonant photoemission of transition metal complexes}}, url = {{http://dx.doi.org/10.1103/PhysRevResearch.3.033030}}, doi = {{10.1103/PhysRevResearch.3.033030}}, volume = {{3}}, year = {{2021}}, }