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Spin propensity in resonant photoemission of transition metal complexes

Temperton, Robert H. LU ; Quevedo, Wilson ; Seidel, Robert ; Schnadt, Joachim LU orcid ; Persson, Petter LU and Uhlig, Jens LU orcid (2021) In Physical Review Research 3(3).
Abstract
Resonant photoelectron spectroscopy (RPES) has been used to probe electronic structure properties of the closed-shell [FeII(CN)6]4− and open-shell [FeIII(CN)6]3− prototype transition metal complexes in aqueous solution. Site-selective Fe 2p (L-edge) RPES mapsprovide new insight into spin-coupling processes at the core-excited metal centers, with autoionization of [FeIII(CN)6]3− showing a dramatic (∼4×)
singlet versus triplet final-state enhancement. This shows that RPES
provides unique opportunities to study spin-dependent electronic
properties in transition metal based functional materials.
Please use this url to cite or link to this publication:
author
; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physical Review Research
volume
3
issue
3
article number
033030
publisher
American Physical Society
external identifiers
  • scopus:85115903910
ISSN
2643-1564
DOI
10.1103/PhysRevResearch.3.033030
language
English
LU publication?
yes
additional info
Publisher Copyright: © 2021 authors. Published by the American Physical Society.
id
6984ecf1-a147-47fd-9dcc-db54e94c80ec
date added to LUP
2021-10-13 16:01:37
date last changed
2025-10-14 13:02:23
@article{6984ecf1-a147-47fd-9dcc-db54e94c80ec,
  abstract     = {{Resonant photoelectron spectroscopy (RPES) has been used to probe electronic structure properties of the closed-shell [FeII(CN)6]4− and open-shell [FeIII(CN)6]3− prototype transition metal complexes in aqueous solution. Site-selective Fe 2p (L-edge) RPES mapsprovide new insight into spin-coupling processes at the core-excited metal centers, with autoionization of [FeIII(CN)6]3− showing a dramatic (∼4×)<br>
 singlet versus triplet final-state enhancement. This shows that RPES <br>
provides unique opportunities to study spin-dependent electronic <br>
properties in transition metal based functional materials.}},
  author       = {{Temperton, Robert H. and Quevedo, Wilson and Seidel, Robert and Schnadt, Joachim and Persson, Petter and Uhlig, Jens}},
  issn         = {{2643-1564}},
  language     = {{eng}},
  number       = {{3}},
  publisher    = {{American Physical Society}},
  series       = {{Physical Review Research}},
  title        = {{Spin propensity in resonant photoemission of transition metal complexes}},
  url          = {{http://dx.doi.org/10.1103/PhysRevResearch.3.033030}},
  doi          = {{10.1103/PhysRevResearch.3.033030}},
  volume       = {{3}},
  year         = {{2021}},
}