Absolute core-level binding energy shifts between atom and solid : The Born-Haber cycle revisited for free nanoscale metal clusters
Tchaplyguine, Maxim LU ; Peredkov, S. LU ; Rosso, Aldana LU ; Bradeanu, I. ; Öhrwall, Gunnar LU
; Legendre, Sébastien
LU
; Ristinmaa Sörensen, Stacey
LU
; Mårtensson, Nils
LU
; Svensson, S.
LU
and Björneholm, O.
LU
(2008)
In Journal of Electron Spectroscopy and Related Phenomena
166-167(1-3 C).
p.38-44
- Abstract (Swedish)
- Abstract in Undetermined
Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely
approximating the infinite solid, have been experimentally derived for several elemental metals. The
cluster core-level binding energies in question have been determined relative to the vacuum level using
synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable
agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest
uncertainty factors defining the discrepancies between the experiment and the model, such as the difference
in the multiplet structure of... (More) - Abstract in Undetermined
Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely
approximating the infinite solid, have been experimentally derived for several elemental metals. The
cluster core-level binding energies in question have been determined relative to the vacuum level using
synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable
agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest
uncertainty factors defining the discrepancies between the experiment and the model, such as the difference
in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster
work functions, and the metal solvation energy, are discussed. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/965632
- author
- Tchaplyguine, Maxim
LU
; Peredkov, S.
LU
; Rosso, Aldana
LU
; Bradeanu, I.
; Öhrwall, Gunnar
LU
; Legendre, Sébastien
LU
; Ristinmaa Sörensen, Stacey
LU
; Mårtensson, Nils
LU
; Svensson, S.
LU
and Björneholm, O.
LU
- organization
- publishing date
- 2008-11
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Nanoscale clusters, Electron spectroscopy, Electronic structure
- in
- Journal of Electron Spectroscopy and Related Phenomena
- volume
- 166-167
- issue
- 1-3 C
- pages
- 7 pages
- publisher
- Elsevier
- external identifiers
-
- wos:000261354000007
- scopus:54849430338
- ISSN
- 0368-2048
- DOI
- 10.1016/j.elspec.2008.05.001
- language
- English
- LU publication?
- yes
- id
- 1779d352-ee6f-463c-8aaa-3c6b317bf336 (old id 965632)
- date added to LUP
- 2016-04-01 13:10:27
- date last changed
- 2022-01-27 17:45:28
@article{1779d352-ee6f-463c-8aaa-3c6b317bf336,
abstract = {{<b>Abstract in Undetermined</b><br/><br>
Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely<br/><br>
approximating the infinite solid, have been experimentally derived for several elemental metals. The<br/><br>
cluster core-level binding energies in question have been determined relative to the vacuum level using<br/><br>
synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable<br/><br>
agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest<br/><br>
uncertainty factors defining the discrepancies between the experiment and the model, such as the difference<br/><br>
in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster<br/><br>
work functions, and the metal solvation energy, are discussed.}},
author = {{Tchaplyguine, Maxim and Peredkov, S. and Rosso, Aldana and Bradeanu, I. and Öhrwall, Gunnar and Legendre, Sébastien and Ristinmaa Sörensen, Stacey and Mårtensson, Nils and Svensson, S. and Björneholm, O.}},
issn = {{0368-2048}},
keywords = {{Nanoscale clusters; Electron spectroscopy; Electronic structure}},
language = {{eng}},
number = {{1-3 C}},
pages = {{38--44}},
publisher = {{Elsevier}},
series = {{Journal of Electron Spectroscopy and Related Phenomena}},
title = {{Absolute core-level binding energy shifts between atom and solid : The Born-Haber cycle revisited for free nanoscale metal clusters}},
url = {{http://dx.doi.org/10.1016/j.elspec.2008.05.001}},
doi = {{10.1016/j.elspec.2008.05.001}},
volume = {{166-167}},
year = {{2008}},
}