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Absolute core-level binding energy shifts between atom and solid : The Born-Haber cycle revisited for free nanoscale metal clusters

Tchaplyguine, Maxim LU ; Peredkov, S. LU ; Rosso, Aldana LU ; Bradeanu, I.; Öhrwall, Gunnar LU ; Legendre, Sébastien LU ; Ristinmaa Sörensen, Stacey LU ; Mårtensson, Nils LU ; Svensson, S. LU and Björneholm, O. LU (2008) In Journal of Electron Spectroscopy and Related Phenomena 166-167(1-3 C). p.38-44
Abstract (Swedish)
Abstract in Undetermined

Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely

approximating the infinite solid, have been experimentally derived for several elemental metals. The

cluster core-level binding energies in question have been determined relative to the vacuum level using

synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable

agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest

uncertainty factors defining the discrepancies between the experiment and the model, such as the difference

in the multiplet structure of... (More)
Abstract in Undetermined

Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely

approximating the infinite solid, have been experimentally derived for several elemental metals. The

cluster core-level binding energies in question have been determined relative to the vacuum level using

synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable

agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest

uncertainty factors defining the discrepancies between the experiment and the model, such as the difference

in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster

work functions, and the metal solvation energy, are discussed. (Less)
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Nanoscale clusters, Electron spectroscopy, Electronic structure
in
Journal of Electron Spectroscopy and Related Phenomena
volume
166-167
issue
1-3 C
pages
7 pages
publisher
Elsevier
external identifiers
  • wos:000261354000007
  • scopus:54849430338
ISSN
0368-2048
DOI
10.1016/j.elspec.2008.05.001http://dx.doi.org/10.1016/j.elspec.2008.05.001
language
English
LU publication?
yes
id
1779d352-ee6f-463c-8aaa-3c6b317bf336 (old id 965632)
date added to LUP
2012-06-13 10:18:40
date last changed
2017-03-31 15:45:16
@article{1779d352-ee6f-463c-8aaa-3c6b317bf336,
  abstract     = {<b>Abstract in Undetermined</b><br/><br>
Core-level binding energy shifts between the free atomand corresponding large clusters, the latter closely<br/><br>
approximating the infinite solid, have been experimentally derived for several elemental metals. The<br/><br>
cluster core-level binding energies in question have been determined relative to the vacuum level using<br/><br>
synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable<br/><br>
agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest<br/><br>
uncertainty factors defining the discrepancies between the experiment and the model, such as the difference<br/><br>
in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster<br/><br>
work functions, and the metal solvation energy, are discussed.},
  author       = {Tchaplyguine, Maxim and Peredkov, S. and Rosso, Aldana and Bradeanu, I. and Öhrwall, Gunnar and Legendre, Sébastien and Ristinmaa Sörensen, Stacey and Mårtensson, Nils and Svensson, S. and Björneholm, O.},
  issn         = {0368-2048},
  keyword      = {Nanoscale clusters,Electron spectroscopy,Electronic structure},
  language     = {eng},
  number       = {1-3 C},
  pages        = {38--44},
  publisher    = {Elsevier},
  series       = {Journal of Electron Spectroscopy and Related Phenomena},
  title        = {Absolute core-level binding energy shifts between atom and solid : The Born-Haber cycle revisited for free nanoscale metal clusters},
  url          = {http://dx.doi.org/10.1016/j.elspec.2008.05.001http://dx.doi.org/10.1016/j.elspec.2008.05.001},
  volume       = {166-167},
  year         = {2008},
}