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Fractionation of Nanoparticle Matter in Red Wines Using Asymmetrical Flow Field-Flow Fractionation

Osorio-Macías, Daniel E. LU ; Song, Dongsup ; Thuvander, Johan LU ; Ferrer-Gallego, Raúl ; Choi, Jaeyeong LU orcid ; Peñarrieta, J. Mauricio ; Nilsson, Lars LU ; Lee, Seungho and Bergenståhl, Björn LU (2020) In Journal of Agricultural and Food Chemistry 68(49). p.14564-14576
Abstract
The particle matter of wine is mainly composed of wine colloids and macromolecules. The present work develops a methodology using asymmetrical flow field-flow fractionation coupled with multi-angle light scattering, differential refractive index detector, and ultraviolet detector (AsFlFFF−MALS−dRI−UV) for the fractionation and determination of the molar mass, the hydrodynamic radius, and the apparent densities of the aggregates and macromolecules present in wine samples. The results from a set of six Argentinian high-altitude wines showed two main populations: the first population composed of wine colloids with higher UV-specific absorptivity and the second population composed of polysaccharides, such as arabinogalactans. The conformation... (More)
The particle matter of wine is mainly composed of wine colloids and macromolecules. The present work develops a methodology using asymmetrical flow field-flow fractionation coupled with multi-angle light scattering, differential refractive index detector, and ultraviolet detector (AsFlFFF−MALS−dRI−UV) for the fractionation and determination of the molar mass, the hydrodynamic radius, and the apparent densities of the aggregates and macromolecules present in wine samples. The results from a set of six Argentinian high-altitude wines showed two main populations: the first population composed of wine colloids with higher UV-specific absorptivity and the second population composed of polysaccharides, such as arabinogalactans. The conformation results showed that population 1 consists of small and dense particles, while population 2 showed high molar masses and lower densities. The results demonstrated the use of AsFlFFF as a new, effective method for the fractionation and characterization of wine colloids and wine macromolecules in red wines with further potential applications. (Less)
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author
; ; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
AsFlFFF, wine colloids, wine macromolecules, anthocyanin, polysaccharides
in
Journal of Agricultural and Food Chemistry
volume
68
issue
49
pages
13 pages
publisher
The American Chemical Society (ACS)
external identifiers
  • scopus:85097572655
ISSN
0021-8561
DOI
10.1021/acs.jafc.9b07251
language
English
LU publication?
yes
id
a413523e-241f-40de-8e93-1e249be65e8a
date added to LUP
2022-04-19 15:19:02
date last changed
2023-12-21 10:10:21
@article{a413523e-241f-40de-8e93-1e249be65e8a,
  abstract     = {{The particle matter of wine is mainly composed of wine colloids and macromolecules. The present work develops a methodology using asymmetrical flow field-flow fractionation coupled with multi-angle light scattering, differential refractive index detector, and ultraviolet detector (AsFlFFF−MALS−dRI−UV) for the fractionation and determination of the molar mass, the hydrodynamic radius, and the apparent densities of the aggregates and macromolecules present in wine samples. The results from a set of six Argentinian high-altitude wines showed two main populations: the first population composed of wine colloids with higher UV-specific absorptivity and the second population composed of polysaccharides, such as arabinogalactans. The conformation results showed that population 1 consists of small and dense particles, while population 2 showed high molar masses and lower densities. The results demonstrated the use of AsFlFFF as a new, effective method for the fractionation and characterization of wine colloids and wine macromolecules in red wines with further potential applications.}},
  author       = {{Osorio-Macías, Daniel E. and Song, Dongsup and Thuvander, Johan and Ferrer-Gallego, Raúl and Choi, Jaeyeong and Peñarrieta, J. Mauricio and Nilsson, Lars and Lee, Seungho and Bergenståhl, Björn}},
  issn         = {{0021-8561}},
  keywords     = {{AsFlFFF; wine colloids; wine macromolecules; anthocyanin; polysaccharides}},
  language     = {{eng}},
  month        = {{11}},
  number       = {{49}},
  pages        = {{14564--14576}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Journal of Agricultural and Food Chemistry}},
  title        = {{Fractionation of Nanoparticle Matter in Red Wines Using Asymmetrical Flow Field-Flow Fractionation}},
  url          = {{http://dx.doi.org/10.1021/acs.jafc.9b07251}},
  doi          = {{10.1021/acs.jafc.9b07251}},
  volume       = {{68}},
  year         = {{2020}},
}