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- 2019
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Mark
Chalcogenide-capped triiron clusters [Fe3(CO)9(μ3-E)2], [Fe3(CO)7(μ3-CO)(μ3-E)(μ-dppm)] and [Fe3(CO)7(μ3-E)2(μ-dppm)] (E = S, Se) as proton-reduction catalysts
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- Contribution to journal › Article
- 2016
-
Mark
Hydrogenase biomimetics with redox-active ligands : Electrocatalytic proton reduction by [Fe2(CO)4(κ2-diamine)(μ-edt)] (diamine = 2,2′-bipy, 1,10-phen)
(
- Contribution to journal › Article
-
Mark
Thermal transformations of tris(2-thienyl)phosphine (PTh3) at low-valent ruthenium cluster centers : Part I. Carbon-hydrogen, carbon-phosphorus and carbon-sulfur bond activation yielding Ru3(CO)8L{μ-Th2P(C4H2S)}(μ-H) (L = CO, PTh3), Ru3(CO)7(μ-PTh2)2(μ3-η2-C4H2S), Ru4(CO)9(μ-CO)2(μ4-η2-C4H2S)(μ4-PTh) and Ru5(CO)11(μ-PTh2)(μ4-η4-C4H3)(μ4-S)
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- Contribution to journal › Article
- 2015
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Mark
Phosphine addition to the sigma,pi-thienyl complex [Fe-2(CO)(6)(mu-Th)(mu-PTh2)] (Th = C4H3S): Carbonyl substitution and migratory carbonyl insertion to give the thienyl-acyl complexes [Fe-2(CO)(4)(diphosphine)(mu-O=C-Th)(mu-PTh2)]
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- Contribution to journal › Article
- 2014
-
Mark
Reactions of the sigma,pi-furyl complex [Fe-2(CO)(6)(mu-Fu)(mu-PFu(2))] (Fu = C4H3O) with phosphines: Carbonyl substitution, migratory carbonyl insertion and cyclometallation-induced furan elimination
(
- Contribution to journal › Article
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Mark
Bioinspired Hydrogenase Models: The Mixed-Valence Triiron Complex [Fe3(CO)7(μ-edt)2] and Phosphine Derivatives [Fe3(CO)7-x (PPh3) x (μ-edt)2] (x = 1, 2) and [Fe3(CO)5(κ(2)-diphosphine)(μ-edt)2] as Proton Reduction Catalysts.
(
- Contribution to journal › Article
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Mark
A comparative study of the reactivity of the lightly stabilized cluster [Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphine
(
- Contribution to journal › Article
-
Mark
Synthesis of [Ru-3(CO)(9)(mu-dppf){P(C4H3E)(3)}] (E = O, S) and thermally induced cyclometalation to form [(mu-H)Ru-3(CO)(7)(mu-dppf){mu(3)-( C4H3E)(2)P(C4H2E)}] (dppf=1,1 '-bis(diphenylphosphino) ferrocene)
(
- Contribution to journal › Article
- 2013
-
Mark
Generation of sigma,pi-furyl and thienyl ligands at di-iron centers via facile phosphorus-carbon bond cleavage: Synthesis and molecular structures of [Fe-2(CO)(6)(mu-eta(1),eta(2)-C4H3E){mu-P(C4H3E)(2)}] (E = O, S)
(
- Contribution to journal › Article
- 2011
-
Mark
Unsymmetrical alkyne binding to a triruthenium centre: Oxidative-addition of diphenyl ditelluride to the furyne cluster [Ru-3(CO)(7)(mu-H)(mu(3)-eta(2)-C4H2O){mu-P(C4H3O)(2)}(mu-dppm)]
(
- Contribution to journal › Article
-
Mark
Reaction of tri(2-furyl)phosphine with triosmium clusters: C-H and P-C activation to afford furyne and phosphinidene ligands
(
- Contribution to journal › Article
- 2010
-
Mark
Cluster chemistry in the Noughties: new developments and their relationship to nanoparticles
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- Contribution to journal › Article
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Mark
Carbon-hydrogen bond activation of phenyldi(2-thienyl)phosphine at a triosmium cluster centre
(
- Contribution to journal › Article
- 2009
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Mark
Reactivity of the triruthenium ortho-metalated cluster [Ru-3(CO)(9){mu(3)- eta(1), kappa(1),kappa(2)-PhP( C6H4) CH2PPh}] with tri(2-thienyl) phosphine and tri( 2-furyl) phosphine: Formation of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine complexes via phosphorus-carbon bond formation
(
- Contribution to journal › Article
-
Mark
Activation of tri(2-furyl)phosphine at a dirhenium centre: Formation of phosphido-bridged dirhenium complexes
(
- Contribution to journal › Article
-
Mark
Reactivity of phenyldi(2-thienyl) phosphine towards group 7 metal carbonyls: Carbon-phosphorus bond activation
(
- Contribution to journal › Article
-
Mark
Carbon-Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers
(
- Contribution to journal › Article
- 2008
-
Mark
Reaction of [Ru-3(CO)(12)] with tri(2-furyl)phosphine: Di- and tri-substituted triruthenium and phosphido-bridged diruthenium complexes
(
- Contribution to journal › Article
-
Mark
Reactivity of triruthenium thiophyne and furyne clusters: competitive S-C and P-C bond cleavage reactions and the generation of highly unsymmetrical alkyne ligands
(
- Contribution to journal › Article
- 2007
-
Mark
New ruthenium carbonyl clusters containing unusual mu(5)-sulfido-, mu(4)-benzyne-, and thianthrene-derived ligands: Insertion of ruthenium into the thianthrene ring by C-S activation
(
- Contribution to journal › Article
- 2004
-
Mark
Oxidative addition of silanes R3SiH to the unsaturated cluster [Os3(µ-H){µ3-Ph2PCH2PPh(C6H4)}(CO)8]: Evidence for reversible silane formation in the dynamic behaviour of [Os3(µ-H)(SiR3)(CO)9(µ-dppm)]
(
- Contribution to journal › Article