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The effect of free convection on apparent vitamin degradation kinetics

Lalwani, Shruti LU ; Glantz, Maria LU ; Paulsson, Marie LU and Håkansson, Andreas LU (2021) In Food and Bioproducts Processing 130. p.182-194
Abstract

Experimentally determined vitamin degradation kinetic parameters are vital input for process optimization, e.g., of nutrient rich beverages such as milk and fruit juices. The standard method of obtaining these parameters is to subject a test-tube of the nutrient (in its food matrix) to a water bath at elevated temperatures and measure remaining concentration as a function of time. It is well known that accurate kinetic fitting requires measuring the temperature inside the test tube as a function of time (due to lag it is not identical to the water-bath temperature), and this is included in contemporary studies. However, the importance of axial temperature gradients for valid kinetic parameter estimations has not been discussed to the... (More)

Experimentally determined vitamin degradation kinetic parameters are vital input for process optimization, e.g., of nutrient rich beverages such as milk and fruit juices. The standard method of obtaining these parameters is to subject a test-tube of the nutrient (in its food matrix) to a water bath at elevated temperatures and measure remaining concentration as a function of time. It is well known that accurate kinetic fitting requires measuring the temperature inside the test tube as a function of time (due to lag it is not identical to the water-bath temperature), and this is included in contemporary studies. However, the importance of axial temperature gradients for valid kinetic parameter estimations has not been discussed to the same extent. This contribution combines experiments and physical modelling to show how an axial temperature gradient evolves in a test tube (R = 13 mm, Z = 75 mm), due to free convection currents (T – T0 = 57–71 °C). Consequently, the test tube temperature is not uniform in such an experiment. Thus, the positioning of the thermocouple in a test-tube-in-water bath experiment is essential for ensuring a valid estimation of the kinetic parameters. Simulations suggest that positioning it half-way between top and bottom is a suitable best practice.

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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Beverages, Convective heat transfer, Free convection, Vitamin degradation
in
Food and Bioproducts Processing
volume
130
pages
13 pages
publisher
Elsevier
external identifiers
  • scopus:85116938510
ISSN
0960-3085
DOI
10.1016/j.fbp.2021.09.015
language
English
LU publication?
yes
additional info
Funding Information: Financial support was received from the Swedish Farmers? Foundation for Agricultural Research, Sweden [grant number O-17-20-941]. Funding Information: Financial support was received from the Swedish Farmers’ Foundation for Agricultural Research , Sweden [grant number O-17-20-941 ]. Publisher Copyright: © 2021 The Author(s)
id
b7da0054-dc8f-4f12-8de4-598e577d58d2
date added to LUP
2021-10-25 07:32:41
date last changed
2023-12-22 04:42:56
@article{b7da0054-dc8f-4f12-8de4-598e577d58d2,
  abstract     = {{<p>Experimentally determined vitamin degradation kinetic parameters are vital input for process optimization, e.g., of nutrient rich beverages such as milk and fruit juices. The standard method of obtaining these parameters is to subject a test-tube of the nutrient (in its food matrix) to a water bath at elevated temperatures and measure remaining concentration as a function of time. It is well known that accurate kinetic fitting requires measuring the temperature inside the test tube as a function of time (due to lag it is not identical to the water-bath temperature), and this is included in contemporary studies. However, the importance of axial temperature gradients for valid kinetic parameter estimations has not been discussed to the same extent. This contribution combines experiments and physical modelling to show how an axial temperature gradient evolves in a test tube (<i>R</i> = 13 mm, <i>Z</i> = 75 mm), due to free convection currents (T<sub>∞</sub> – T<sub>0</sub> = 57–71 °C). Consequently, the test tube temperature is not uniform in such an experiment. Thus, the positioning of the thermocouple in a test-tube-in-water bath experiment is essential for ensuring a valid estimation of the kinetic parameters. Simulations suggest that positioning it half-way between top and bottom is a suitable best practice.</p>}},
  author       = {{Lalwani, Shruti and Glantz, Maria and Paulsson, Marie and Håkansson, Andreas}},
  issn         = {{0960-3085}},
  keywords     = {{Beverages; Convective heat transfer; Free convection; Vitamin degradation}},
  language     = {{eng}},
  pages        = {{182--194}},
  publisher    = {{Elsevier}},
  series       = {{Food and Bioproducts Processing}},
  title        = {{The effect of free convection on apparent vitamin degradation kinetics}},
  url          = {{http://dx.doi.org/10.1016/j.fbp.2021.09.015}},
  doi          = {{10.1016/j.fbp.2021.09.015}},
  volume       = {{130}},
  year         = {{2021}},
}