Dip-and-pull ambient pressure photoelectron spectroscopy as a spectroelectrochemistry tool for probing molecular redox processes
(2022) In Journal of Chemical Physics 157(24).- Abstract
Ambient pressure x-ray photoelectron spectroscopy (APXPS) can provide a compelling platform for studying an analyte's oxidation and reduction reactions in solutions. This paper presents proof-of-principle operando measurements of a model organometallic complex, iron hexacyanide, in an aqueous solution using the dip-and-pull technique. The data demonstrates that the electrochemically active liquid meniscuses on the working electrodes can undergo controlled redox reactions which were observed using APXPS. A detailed discussion of several critical experimental considerations is included as guidance for anyone undertaking comparable experiments.
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- author
- organization
-
- MAX IV Laboratory
- LTH Profile Area: Photon Science and Technology
- LTH Profile Area: Nanoscience and Semiconductor Technology
- Chemical Physics
- NanoLund: Centre for Nanoscience
- LINXS - Institute of advanced Neutron and X-ray Science
- Synchrotron Radiation Research
- Department of Physics
- Combustion Physics
- Computational Chemistry
- publishing date
- 2022-12-28
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 157
- issue
- 24
- article number
- 244701
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- pmid:36586986
- scopus:85144634057
- ISSN
- 0021-9606
- DOI
- 10.1063/5.0130222
- language
- English
- LU publication?
- yes
- id
- ec825afb-bd65-47b2-8e9c-284f0bf10ee3
- date added to LUP
- 2023-01-04 16:12:01
- date last changed
- 2024-06-13 22:45:47
@article{ec825afb-bd65-47b2-8e9c-284f0bf10ee3, abstract = {{<p>Ambient pressure x-ray photoelectron spectroscopy (APXPS) can provide a compelling platform for studying an analyte's oxidation and reduction reactions in solutions. This paper presents proof-of-principle operando measurements of a model organometallic complex, iron hexacyanide, in an aqueous solution using the dip-and-pull technique. The data demonstrates that the electrochemically active liquid meniscuses on the working electrodes can undergo controlled redox reactions which were observed using APXPS. A detailed discussion of several critical experimental considerations is included as guidance for anyone undertaking comparable experiments.</p>}}, author = {{Temperton, Robert H. and Kawde, Anurag and Eriksson, Axl and Wang, Weijia and Kokkonen, Esko and Jones, Rosemary and Gericke, Sabrina Maria and Zhu, Suyun and Quevedo, Wilson and Seidel, Robert and Schnadt, Joachim and Shavorskiy, Andrey and Persson, Petter and Uhlig, Jens}}, issn = {{0021-9606}}, language = {{eng}}, month = {{12}}, number = {{24}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Dip-and-pull ambient pressure photoelectron spectroscopy as a spectroelectrochemistry tool for probing molecular redox processes}}, url = {{http://dx.doi.org/10.1063/5.0130222}}, doi = {{10.1063/5.0130222}}, volume = {{157}}, year = {{2022}}, }